Cobalt(iii)-catalyzed 1,4-addition of C–H bonds of oximes to maleimides†,Organic Chemistry Frontiers

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Cobalt(iii)-catalyzed 1,4-addition of C–H bonds of oximes to maleimides†
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2017-09-27 00:00:00 , DOI: 10.1039/c7qo00687j
Xiangxiang Chen _{1,

2,

3,

4,

5} , Jiangtao Ren _{1,

2,

3,

4,

5} , Hu Xie _{1,

2,

3,

4,

5} , Wei Sun _{1,

2,

3,

4,

5} , Meng Sun _{1,

2,

3,

4,

5} , Biao Wu _{1,

2,

3,

4,

5}

Affiliation

Oxime directed cobalt-catalyzed arene sp² C–H bond conjugation addition to maleimide was reported, the reaction showed great tolerance to different functional groups, and various succinimide derivatives were efficiently produced. This protocol exhibited specific reactivity with only producing a mono-C–H bond addition product and no external base was needed, which suggested a unique reactivity of this Co-based catalytic system.

中文翻译：

钴（iii）催化肟中的C–H键与马来酰亚胺的1,4-加成†

据报道，肟肟对钴催化的芳烃sp ² C–H键与马来酰亚胺共轭键合，该反应对不同的官能团具有很强的耐受性，并且可以高效地生产各种琥珀酰亚胺衍生物。该方案显示出特定的反应性，仅产生单C–H键加成产物，而无需外部碱，这表明该Co基催化体系具有独特的反应性。

更新日期：2017-09-27

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