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A novel S, N dual doped carbon catalyst for acetylene hydrochlorination
Applied Catalysis A: General ( IF 4.7 ) Pub Date : 2017-09-22 , DOI: 10.1016/j.apcata.2017.09.025
Jian Wang , Fei Zhao , Chunli Zhang , Lihua Kang , Mingyuan Zhu

In this study, a sulphur and nitrogen dual-doped carbon catalyst was prepared via an easy route with p-phenyldiamine and (NH4)2S2O8 as the nitrogen and sulphur source, respectively. The obtained catalyst displayed efficient acetylene conversion for acetylene hydrochlorination, and the presence of sulphur enhanced the catalytic activity of the nitrogen-doped carbon catalyst. These catalysts show that sulphur and nitrogen have a synergistic effect for acetylene hydrochlorination. Furthermore, because of the addition of different sulphur contents, the pyrrolic N content causes certain changes in the catalysts, resulting in differences in the catalytic activity. Theoretical investigations reveal that the adsorption ability of C2H2 was enhanced by the doping of the S and N-doped carbon catalyst. This is an environmentally friendly catalyst with a broad development prospect and is cheap and easy to obtain.



中文翻译:

一种新型的乙,N双掺杂碳催化剂,用于乙炔盐酸盐的氯化反应

在这项研究中,通过对苯二胺和(NH 42 S 2 O 8的简便方法制备了硫和氮双掺杂碳催化剂。分别作为氮和硫的来源 所获得的催化剂显示出用于乙炔氢氯化的有效乙炔转化,并且硫的存在增强了氮掺杂碳催化剂的催化活性。这些催化剂表明,硫和氮对于乙炔氢氯化具有协同作用。此外,由于添加了不同的硫含量,吡咯N含量引起催化剂的某些变化,从而导致催化活性的差异。理论研究表明,掺杂S和N掺杂的碳催化剂可提高C 2 H 2的吸附能力。这是一种环境友好的催化剂,具有广阔的发展前景,并且价格便宜且易于获得。

更新日期:2017-09-22
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