Scandium-catalyzed C(sp3)–H alkylation of N,N-dimethyl anilines with alkenes†,Organic Chemistry Frontiers

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Scandium-catalyzed C(sp3)–H alkylation of N,N-dimethyl anilines with alkenes†
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2017-09-20 00:00:00 , DOI: 10.1039/c7qo00718c
Hongjie Gao _{1,

2,

3,

4,

5} , Jianhong Su _{1,

2,

3,

4,

5} , Pengfei Xu _{1,

2,

3,

4,

5} , Xin Xu _{1,

2,

3,

4,

5}

Affiliation

A scandium complex based on a new type of tridentate ligand enabled an atom- and step-economical C(sp³)–H addition of N,N-dimethyl anilines to a variety of unactivated alkenes affording branched products for the first time. A cationic o-dimethylaminophenyl scandium species was isolated and confirmed as the catalytic intermediate in this transformation.

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