Significant progress has been achieved in the synthesis of covalent organic frameworks (COFs) or mesoporous polymers (MPs) with various application potentials in the past decade. Integration of tetrapyrrole chromophores, i.e. porphyrin and phthalocyanine, into the conjugated two-dimensional COFs/MPs with the help of conjugated linking units renders the possibility of coupling the addressable tetrapyrrole functionality with general COF-based functional properties, resulting in a wide range of applications in heterogeneous catalysis, energy storage and conversion, environment-related opportunities, photoelectric and electronic devices. This paper highlights the progress achieved in this field and meanwhile gives some original perspectives that will stimulate further advances toward both fundamental research and application efforts.

在过去的十年中，在具有各种应用潜力的共价有机骨架（COF）或中孔聚合物（MPs）的合成方面取得了重大进展。在共轭二维连接单元的帮助下，将四吡咯发色团（即卟啉和酞菁）整合到共轭二维COF / MP中，使可寻址的四吡咯官能团与一般的基于COF的功能特性偶联成为可能，从而导致了广泛的应用在多相催化，能量存储和转化，与环境有关的机会，光电和电子设备方面。本文着重介绍了该领域所取得的进展，同时给出了一些独到的见解，这些观点将刺激基础研究和应用领域的进一步发展。