From Precision Synthesis of Block Copolymers to Properties and Applications of Nanoparticles,Angewandte Chemie International Edition

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From Precision Synthesis of Block Copolymers to Properties and Applications of Nanoparticles
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2018-01-15 , DOI: 10.1002/anie.201705019
Xiao Li _{1,

2} , James Iocozzia ₂ , Yihuang Chen ₂ , Shiqiang Zhao ₂ , Xun Cui ₂ , Wei Wang _{2,

3} , Haifeng Yu ₁ , Shaoliang Lin ₃ , Zhiqun Lin ₂

Affiliation

Inorganic nanoparticles have become a research focus in numerous fields because of their unique properties that distinguish them from their bulk counterparts. Controlling the size and shape of nanoparticles is an essential aspect of nanoparticle synthesis. Preparing inorganic nanoparticles by using block copolymer templates is one of the most reliable routes for tuning the size and shape of nanoparticles with a high degree of precision. In this Review, we discuss recent progress in the design of block copolymer templates for crafting spherical inorganic nanoparticles including compact, hollow, and core–shell varieties. The templates are divided into two categories: micelles self‐assembled from linear block copolymers and unimolecular star‐shaped block copolymers. The precise control over the size and morphology of nanoparticles is highlighted as well as the useful properties and applications of such inorganic nanoparticles.

中文翻译：

从嵌段共聚物的精确合成到纳米粒子的性能与应用

无机纳米粒子由于其独特的性质使其区别于本体的纳米粒子而成为许多领域的研究重点。控制纳米颗粒的尺寸和形状是纳米颗粒合成的重要方面。通过使用嵌段共聚物模板制备无机纳米粒子是最高精度的纳米粒子尺寸和形状调整方法之一。在本综述中，我们讨论了用于制备球形无机纳米粒子（包括致密，中空和核壳型）的嵌段共聚物模板设计的最新进展。模板分为两类：由线性嵌段共聚物自组装的胶束和单分子星形嵌段共聚物。

更新日期：2018-01-15

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