Recently, the development of clean sustainable energy conversion and storage technologies to deal with environmental pollution and the forthcoming energy crisis has attracted much attention in the energy research community and coordination chemistry has played a key role in this very active research field. Metal coordination materials are known as one of the best active materials for high-performance supercapacitors due to their outstanding specific capacitance, long cycle life, and good electrochemical reversibility. This review mainly introduces the synthesis of metal coordination materials (metal–organic frameworks, Prussian blue, polyoxometalates, oxalate, their composites and derivatives) with the focus on their application in supercapacitors.

近来，用于处理环境污染和即将到来的能源危机的清洁可持续能源转换和存储技术的发展已在能源研究界引起了广泛关注，并且配位化学在这一非常活跃的研究领域中发挥了关键作用。金属配位材料因其出色的比电容，长循环寿命和良好的电化学可逆性而被公认为是高性能超级电容器的最佳活性材料之一。这篇综述主要介绍了金属配位材料（金属-有机骨架，普鲁士蓝，多金属氧酸盐，草酸盐，它们的复合物和衍生物）的合成，重点是它们在超级电容器中的应用。