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Construction of a photothermal Venus flytrap from conductive polymer bimorphs
NPG Asia Materials ( IF 8.6 ) Pub Date : 2017-07-07 , DOI: 10.1038/am.2017.101
Hanwhuy Lim , Teahoon Park , Jongbeom Na , Chihyun Park , Byeonggwan Kim , Eunkyoung Kim

A photothermally foldable soft bimorph was prepared via the dry transfer of poly(3,4-ethylenedioxythiophene) (PEDOT) doped with tosylate onto a poly(dimethylsiloxane) film. The photothermal folding was optimized via reversible actuation by controlling the thickness of each layer and the temperature increase to afford large deflection and displacement up to 150° and >20 mm, respectively, upon exposure to near-infrared (NIR) light (808 nm). A two-dimensional array of the bimorph converted into complex three-dimensional architectures, such as a Venus flytrap, under light and reversibly unfolded in the dark. Taking advantage of the photothermal nature of PEDOT, a localized heat pocket was generated inside the folding structure. Thus, a Venus flytrap with a hot pocket reaching 100 °C was realized for the first time. The Venus flytrap could trap and move an object within a few seconds of NIR exposure.



中文翻译:

由导电聚合物双晶型物构建光热金星捕蝇器

通过将掺有甲苯磺酸酯的聚(3,4-乙撑二氧噻吩)(PEDOT)干燥转移到聚(二甲基硅氧烷)薄膜上,制备出可光热折叠的软双晶型物。通过控制每一层的厚度和温度升高,通过可逆驱动来优化光热折叠,从而在暴露于近红外(NIR)光(808 nm)时分别提供高达150°和大于20 mm的大偏转和位移。 。双压电晶片的二维阵列在光照下转换为复杂的三维体系结构,例如维纳斯捕蝇器,并在黑暗中可逆地展开。利用PEDOT的光热特性,在折叠结构内部产生了局部热量囊。因此,首次实现了热袋达到100°C的维纳斯捕蝇器。

更新日期:2017-07-08
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