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Quinoxaline-based Y-type acceptors for organic solar cells
Chemical Science ( IF 8.4 ) Pub Date : 2024-05-07 , DOI: 10.1039/d4sc01481b
Meiling Xie 1, 2 , Zhixiang Wei 1, 2 , Kun Lu 1, 2
Affiliation  

Minimizing energy loss plays a critical role in the quest for high-performance organic solar cells (OSCs). However, the origin of large energy loss in OCSs is complicated, involving the strong exciton binding energy of organic semiconductors, nonradiative charge-transfer state decay, defective molecular stacking network, and so on. The recently developed quinoxaline (Qx)-based acceptors have attracted extensive interest due to their low reorganization energy, high structural modification possibilities, and distinctive molecular packing modes, which contribute to reduced energy loss and superior charge generation/transport, thus improving the photovoltaic performance of OSCs. This perspective summarizes the design strategies of Qx-based acceptors (including small-molecule, giant dimeric and polymeric acceptors) and the resulting optoelectronic properties and device performance. In addition, the ternary strategy of introducing Qx-based acceptors as the third component to reduce energy loss is briefly discussed. Finally, some perspectives for the further exploration of Qx-based acceptors toward efficient, stable, and industry-compatible OSCs are proposed.

中文翻译:

用于有机太阳能电池的基于喹喔啉的Y型受体

在寻求高性能有机太阳能电池(OSC)的过程中,最大限度地减少能量损失起着至关重要的作用。然而,OCS中大量能量损失的根源很复杂,涉及有机半导体的强激子结合能、非辐射电荷转移态衰减、有缺陷的分子堆叠网络等。最近开发的基于喹喔啉(Qx)的受体由于其低重组能、高结构修饰可能性和独特的分子堆积模式而引起了广泛的兴趣,这有助于减少能量损失和优异的电荷产生/传输,从而提高光伏性能OSC 的数量。该视角总结了基于Qx的受体(包括小分子、巨型二聚体和聚合受体)的设计策略以及由此产生的光电特性和器件性能。此外,还简要讨论了引入基于Qx的受体作为第三组件以减少能量损失的三元策略。最后,提出了进一步探索基于 Qx 的受体以实现高效、稳定和行业兼容的 OSC 的一些观点。
更新日期:2024-05-07
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