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Solution Dynamics of Covalent Open-[60]Fullerene Dimers
ChemPlusChem ( IF 3.4 ) Pub Date : 2024-05-06 , DOI: 10.1002/cplu.202400260
Shu Okamoto 1 , Yoshifumi Hashikawa 1 , Yasujiro Murata 2
Affiliation  

A prolate ellipsoid model could accurately estimate the size of covalent open-[60]fullerene dimers from translational diffusion coefficients measured in solution. The sp3-linked dimer showed a higher water affinity than the sp2-linked dimer owing to stronger π(fullerene)→σ*(H2O) interactions.

中文翻译:

共价开放-[60]富勒烯二聚体的溶液动力学

长椭球模型可以根据溶液中测量的平移扩散系数准确估计共价开放[60]富勒烯二聚体的大小。由于更强的π(富勒烯)→σ*(H 2 O)相互作用,sp 3连接的二聚体表现出比sp 2连接的二聚体更高的水亲和力。
更新日期:2024-05-06
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