当前位置: X-MOL 学术Org. Chem. Front. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Diastereoselective synthesis of cis-cyclopentane-1,2-diamine derivatives via organophotoredox-catalyzed [3 + 2] cycloadditions
Organic Chemistry Frontiers ( IF 5.4 ) Pub Date : 2024-05-02 , DOI: 10.1039/d4qo00426d
Yang Xu 1 , Yinong Wu 1 , Xufeng Lin 1
Affiliation  

A highly diastereoselective organophotoredox-catalyzed [3 + 2] cycloaddition of N-aryl cyclopropylamines with N-vinylphthalimides was reported. This transformation leads to diverse cis-cyclopentane-1,2-diamine derivatives via a dual catalyst system Eosin Y and Binol-derived phosphoric acid with Et3N as an additive.

中文翻译:

通过有机光氧化还原催化的[3 + 2]环加成非对映选择性合成顺式环戊烷-1,2-二胺衍生物

报道了N-芳基环丙胺与N-乙烯基邻苯二甲酰亚胺的高度非对映选择性有机光氧化还原催化的 [3 + 2] 环加成反应。这种转化通过双催化剂系统曙红 Y 和联醇衍生的磷酸以及 Et 3 N 作为添加剂,产生多种顺式环戊烷-1,2-二胺衍生物。
更新日期:2024-05-02
down
wechat
bug