Herein, the synthesis of homoallylic amines, quinolines, and tetrahydroquinolines has been demonstrated. The domino one‐pot multi‐component approach has been accomplished using Lewis acid‐catalyzed conditions. A useful scaffold construction strategy can be achieved by controlling the electronic effect of aniline rather than relying on reaction conditions. The described method applies to a wide variety of substrates embedded with diverse functional groups and can be extended toward the synthesis of natural products. Suitable control experiments, real‐time NMR studies, and DFT calculations have validated the reported process. The protocol outlines a strategy for synthesizing homoallylic amines and quinolines, controlled by the electronic properties of anilines.

中文翻译：

---

路易斯酸促进的多米诺工艺合成高烯丙基胺、喹啉和四氢喹啉

在此，已经证明了高烯丙胺、喹啉和四氢喹啉的合成。多米诺骨牌一锅多组分方法是使用路易斯酸催化条件完成的。通过控制苯胺的电子效应而不是依赖反应条件可以实现有用的支架构建策略。所述方法适用于嵌入不同官能团的各种底物，并且可以扩展到天然产物的合成。适当的控制实验、实时核磁共振研究和 DFT 计算验证了所报告的过程。该协议概述了合成同烯丙基胺和喹啉的策略，由苯胺的电子特性控制。