当前位置: X-MOL 学术Chem. Commun. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Eosin, blue LEDs and DIPEA are employed in a simple synthesis of (poly)cyclic O,O- and N,O-acetals
Chemical Communications ( IF 4.9 ) Pub Date : 2024-04-30 , DOI: 10.1039/d4cc01175a
Ioannis Papadopoulos 1 , Artemis Bosveli 1 , Tamsyn Montagnon 1 , Ioannis Zachilas 1 , Dimitris Kalaitzakis 1 , Georgios Vassilikogiannakis 1
Affiliation  

A simple procedure for the synthesis of (poly)cyclic O,O- and N,O-acetals from various enol ethers, N-acyl enamines or Boc-protected enamines has been developed. The key step is a photocatalytic Stork–Ueno-type cylization using the very simple metal-free conditions of catalytic eosin, diisopropylamine in the green solvent ethanol with blue LED irradition.

中文翻译:

曙红、蓝色 LED 和 DIPEA 用于(多)环 O,O- 和 N,O-缩醛的简单合成

已经开发出一种从各种烯醇醚、N-酰基烯胺或 Boc 保护的烯胺合成(多)环OO-N , O-缩醛的简单方法。关键步骤是在绿色溶剂乙醇中使用非常简单的无金属催化条件曙红、二异丙胺和蓝色 LED 照射进行光催化 Stork-Ueno 型环化。
更新日期:2024-04-30
down
wechat
bug