The role of allylic substitution reactions is crucial in organic synthesis. Through these reactions, the development of numerous molecular structures with a wide range of applications can be achieved in diverse fields. They also provide an efficient methodology for synthesizing novel heterocyclic compounds with potential as drugs, natural products, and bioactive structures. This review summarizes the research progress in cyclization reactions catalytic allylic substitution for the asymmetric synthesis of heterocyclic compounds over the past five years. The discussion focused on catalytic asymmetric allylic substitutions with nitrogen, oxygen and carbon nucleophiles.

中文翻译：

---

催化烯丙基取代环化反应用于杂环化合物不对称合成的最新进展

烯丙基取代反应在有机合成中至关重要。通过这些反应，可以在不同领域开发出多种具有广泛应用的分子结构。它们还提供了一种有效的方法来合成具有药物、天然产物和生物活性结构潜力的新型杂环化合物。本文综述了近五年来催化烯丙基取代环化反应用于杂环化合物不对称合成的研究进展。讨论重点是氮、氧和碳亲核试剂的催化不对称烯丙基取代。