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Role of Debye temperature in achieving large adiabatic temperature changes at cryogenic temperatures: A case study onPr2In
Physical Review B ( IF 3.7 ) Pub Date : 2024-04-17 , DOI: 10.1103/physrevb.109.l140407
Wei Liu , Franziska Scheibel , Nuno Fortunato , Imants Dirba , Tino Gottschall , Hongbin Zhang , Konstantin Skokov , Oliver Gutfleisch

The excellent magnetic entropy change (ΔST) in the temperature range of 20 77 K due to the first-order phase transition makes Pr2In an intriguing candidate for magnetocaloric hydrogen liquefaction. As an equally important magnetocaloric parameter, the adiabatic temperature change (ΔTad) of Pr2In associated with the first-order phase transition has not yet been reported. In this work, the ΔTad of Pr2In is obtained from heat capacity measurements: 2 K in fields of 2 T and 4.3 K in fields of 5 T. While demonstrating a ΔTad that is not as impressive as its remarkable ΔST, Pr2In exhibits a low Debye temperature (TD) of around 110 K. Based on these two observations, an approach that combines the mean-field and Debye models is developed to study the correlation between ΔTad, one of the most important magnetocaloric parameters, and TD, one important property of a material. The role of TD in achieving large ΔTad is revealed: materials with higher TD tend to exhibit larger ΔTad, particularly in the cryogenic temperature range. This discovery explains the absence of an outstanding ΔTad in Pr2In and can serve as a tool for designing or searching for materials with both a large ΔST and a ΔTad.

中文翻译:

德拜温度在低温下实现大绝热温度变化的作用:Pr2In 的案例研究

优异的磁熵变(ΔS时间)在20的温度范围内77 K 由于一阶相变使得普罗2磁热氢液化的一个有趣的候选者。作为一个同样重要的磁热参数,绝热温度变化(Δ时间Ad) 的普罗2与一级相变相关的现象尚未见报道。在这项工作中,Δ时间Ad普罗2是从热容测量中获得的:2 T 场中为 2 K,5 T 场中为 4.3 K。Δ时间Ad这并不像其非凡的那样令人印象深刻ΔS时间, 普罗2表现出较低的德拜温度(时间D)约为 110 K。基于这两个观测结果,开发了一种结合平均场和德拜模型的方法来研究之间的相关性Δ时间Ad,最重要的磁热参数之一,以及时间D,材料的一个重要属性。的作用时间D在实现大Δ时间Ad揭示:材料具有更高时间D往往表现出较大的Δ时间Ad,特别是在低温范围内。这一发现解释了缺乏杰出的Δ时间Ad普罗2并且可以作为设计或搜索具有大范围材料的工具ΔS时间和一个Δ时间Ad
更新日期:2024-04-17
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