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A Novel Fe-Based Metallic Glass as the Bipolar Plate for Proton Exchange Membrane Fuel Cells
Industrial & Engineering Chemistry Research ( IF 4.2 ) Pub Date : 2024-04-16 , DOI: 10.1021/acs.iecr.3c04265
Chao Su 1 , Chi Zhang 1 , Naiqiang Zhang 1 , Yunlong Zhai 1 , Guanlin Zhang 1 , Ju Liu 1 , Hong Wu 2 , Yanqiang Kong 1 , Tianyi Zhang 1 , Kaiyang Li 1
Affiliation  

A novel metallic glass, Fe50Cr18Mo10C20Si2 (FeMG), is developed and proposed as a potential bipolar plate for proton exchange membrane fuel cells. Its metallic glass nature ensures that there is an oversaturation of Cr and Mo in the substrate and that a stable Cr–Mo–C-rich passive film forms with fewer defects. Therefore, FeMG shows higher impedance, higher stability, higher corrosion resistance, and a lower ion dissolution rate than SS316 during immersion and electrochemical tests. A comparison with Ti-based alloys, stainless steels, and other metallic glasses clearly shows that the novel FeMG has outstanding corrosion resistance and low cost, indicating its great potential for commercialization.

中文翻译:

一种新型铁基金属玻璃作为质子交换膜燃料电池双极板

开发了一种新型金属玻璃 Fe 50 Cr 18 Mo 10 C 20 Si 2 (FeMG),并提议作为质子交换膜燃料电池的潜在双极板。其金属玻璃性质确保了基材中 Cr 和 Mo 的过饱和,并形成稳定的富含 Cr-Mo-C 的钝化膜,且缺陷较少。因此,在浸泡和电化学测试中,FeMG比SS316表现出更高的阻抗、更高的稳定性、更高的耐腐蚀性和更低的离子溶解速率。与钛基合金、不锈钢和其他金属玻璃的比较清楚地表明,新型FeMG具有优异的耐腐蚀性和低成本,表明其巨大的商业化潜力。
更新日期:2024-04-17
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