The synthesis and characterization of porphyrin center regulated three‐dimensional covalent organic frameworks with 2‐fold interpenetrated scu or sqc topology have been investigated. These COFs exhibit unique structural features and properties, making them promising candidates for photocatalytic applications in CO2 reduction and artemisinin synthesis. The porphyrin center serves as an anchor for metal ions, allowing precise control over structures and functions of the frameworks. Furthermore, the metal coordination within the framework imparts desirable catalytic properties, enabling their potential use in photocatalytic reactions. Overall, these porphyrin center regulated metal‐controlled COFs offer exciting opportunities for the development of advanced materials with tailored functionalities.

中文翻译：

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前所未有的 POSS 连接 3D 共价有机框架，具有 scu 或 sqc 拓扑，由卟啉光催化二氧化碳还原中心调控

研究了具有2重互穿scu或sqc拓扑结构的卟啉中心调节的三维共价有机框架的合成和表征。这些COF表现出独特的结构特征和性质，使其成为二氧化碳还原和青蒿素合成中光催化应用的有希望的候选者。卟啉中心充当金属离子的锚，可以精确控制框架的结构和功能。此外，框架内的金属配位赋予了所需的催化性能，使其在光催化反应中具有潜在的用途。总体而言，这些卟啉中心调节的金属控制 COF 为开发具有定制功能的先进材料提供了令人兴奋的机会。