Here we developed PPy/CNT/MOF ternary composites with microtubular structure, which was triggered by both the disassembly of Co-MOF and the reassembly of phosphomolybdate acid (PMA) and the released ligand. As a result, the CNTs and polypyrroles (PPys) are intertwined and deposited on the surface of the composites, forming a core-shell structure. Among the ternary composites, the PM/CNT/MOF-2 electrode (PMA concertation of 5 mM) provides a specific capacitance of 650 F g at 1 A g. The assembled flexible supercapacitor device delivered a high energy density of 68.9 μWh cm (45.9 Wh kg) at power density of 800 μW cm (800 W kg), a good long-term cyclic stability, and superior mechanical flexibility.

中文翻译：

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以球形Co-MOF为牺牲模板的核壳微管PPy/CNT/MOF三元复合材料的制备及电化学性能

在这里，我们开发了具有微管结构的PPy/CNT/MOF三元复合材料，该复合材料是由Co-MOF的分解以及磷钼酸（PMA）和释放的配体的重新组装触发的。结果，碳纳米管和聚吡咯（PPys）相互缠绕并沉积在复合材料的表面，形成核壳结构。在三元复合材料中，PM/CNT/MOF-2 电极（PMA 浓度为 5 mM）在 1 A g 时提供 650 F g 的比电容。组装的柔性超级电容器装置在800 μW cm（800 W kg）的功率密度下提供了68.9 μWh cm（45.9 Wh kg）的高能量密度、良好的长期循环稳定性和优异的机械灵活性。