Here, using the Sonogashira coupling technique, a new fluorescent tetraphenylethene (TPE) and borondipyrromethene (BODIPY)-based CMP (TPE-BODIPY-CMP) was built and developed for usage in supercapacitors and Cu ion detection. XPS, ssNMR, and FTIR techniques were used to validate the presence of the functional groups, aromatic carbons, and atoms [Si, B, C, N, O, and F] in the TPE-BODIPY-CMP framework. In the TPE-BODIPY-CMP, the calculated pore size, S, and carbon residue were 1.52–2.82 nm, 300 m g, and 67%, respectively. as per our electrochemical test, the capacitance stability [83.23% after 5000 cycles], and specific capacity of 176 F g (0.5 A g) for TPE-BODIPY-CMP. We performed photoluminescence (PL) experiments on TPE-BODIPY-CMP to evaluate its capacity in cation detection [Cu, Pb, Al, Cr, Ni, Ce, Mg, Hg, Fe, Fe, Zn, and Ag] and a limit of detection (LOD) of TPE-BODIPY-CMP toward Cu ions was 2.5 × 10 M.

中文翻译：

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含有 BODIPY 和四苯乙烯单元的双功能发光共轭微孔聚合物，可实现高效能量存储和增强 Cu2+ 离子传感

在此，利用 Sonogashira 耦合技术，构建并开发了一种基于荧光四苯乙烯 (TPE) 和硼二吡咯亚甲基 (BODIPY) 的新型 CMP (TPE-BODIPY-CMP)，用于超级电容器和铜离子检测。 XPS、ssNMR 和 FTIR 技术用于验证 TPE-BODIPY-CMP 框架中官能团、芳香碳和原子 [Si、B、C、N、O 和 F] 的存在。在TPE-BODIPY-CMP中，计算出的孔径、S和残炭分别为1.52-2.82 nm、300 m g和67%。根据我们的电化学测试，TPE-BODIPY-CMP 的电容稳定性 [5000 次循环后为 83.23%]，比容量为 176 F g (0.5 A g)。我们对 TPE-BODIPY-CMP 进行了光致发光 (PL) 实验，以评估其检测阳离子 [Cu、Pb、Al、Cr、Ni、Ce、Mg、Hg、Fe、Fe、Zn 和 Ag] 的能力以及限制TPE-BODIPY-CMP 对 Cu 离子的检测 (LOD) 为 2.5 × 10 M。