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Low-cost preparation of temperature-resistant and salt-tolerant amphiphilic carbon dots from a nonionic surfactant and its application in enhanced oil recovery
Carbon ( IF 10.9 ) Pub Date : 2024-04-05 , DOI: 10.1016/j.carbon.2024.119104
Renling Lu , Siyu He , Tengfei Wang , Lu Lai , Mingwei Zhao

Amphiphilic carbon dots (ACDs) were synthesized from nonionic surfactant alkyl glycosides with different alkyl chains by a low-cost method. Moreover, the surface activity of these ACDs (C6-ACDs, C10-ACDs, and C1214-ACDs) was investigated. These ACDs have similar surface tension curves as surfactants, and the surface activity of these ACDs also increases with the alkyl chain length of raw materials. Among these ACDs, C1214-ACDs have the lowest critical micelle concentration (CMC) of 40.00 mg/L, a fifth of the raw material (APG1214). The surface tension of C1214-ACDs is not easily affected by the change in pH. In addition, C1214-ACDs have excellent temperature-resistant and salt-tolerant properties. The interfacial tension of crude oil-water is reduced from 26.59 mN/m to 0.68 mN/m by C1214-ACDs. Furthermore, C1214-ACDs maintains high interfacial activity at cNaCl = 200 g/L and cCaCl2 = 50 g/L, reducing interfacial tension to 0.054 mN/m and 0.048 mN/m.

C1214-ACDs have high oil removal efficiency. After treatment with APG1214, C6-ACDs, C10-ACDs, and C1214-ACDs, the area of the oil film is reduced by 51.0%, 46.6%, 56.2%, and 78.1%, respectively. Moreover, APG1214 and C1214-ACDs reduce the contact angle of water droplets from 107.4° to 60.5° and 45.6°, respectively, indicating the wettability alternation of C1214-ACDs is better than raw material APG1214. Finally, the oil displacement efficiency of C1214-ACDs is 16.6% in the presence of 85 g/L NaCl and 10 g/L CaCl2. Therefore, as temperature-resistant and salt-tolerant nanoparticles with an ultra-small size, ACDs have broad application prospects in enhancing oil recovery in high-temperature and high-salt reservoirs.



中文翻译:

非离子表面活性剂低成本制备耐温耐盐两亲性碳点及其在提高采收率中的应用

以不同烷基链的非离子表面活性剂烷基糖苷为原料,采用低成本方法合成了两亲性碳点(ACD)。此外,研究了这些ACD(C 6 -ACD、C 10 -ACD和C 1214 -ACD)的表面活性。这些ACD具有与表面活性剂相似的表面张力曲线,并且这些ACD的表面活性也随着原料烷基链长度的增加而增加。其中,C 1214 -ACD 的临界胶束浓度 (CMC) 最低,为 40.00 mg/L,是原料 (APG1214) 的五分之一。 C 1214 -ACDs的表面张力不易受pH变化的影响。此外,C 1214 -ACD具有优异的耐温、耐盐性能。 C 1214 -ACD将原油-水的界面张力从 26.59 mN/m 降低至 0.68 mN/m 。此外,C 1214 -ACDs在c NaCl  = 200 g/L和c CaCl2 = 50 g/L时保持高界面活性 ,将界面张力降低至0.054 mN/m和0.048 mN/m。

C 1214 -ACD 具有较高的除油效率。经过APG1214、C 6 -ACDs、C 10 -ACDs和C 1214 -ACDs处理后,油膜面积分别减少了51.0%、46.6%、56.2%和78.1%。此外,APG1214和C 1214 -ACDs将水滴的接触角分别从107.4°降低到60.5°和45.6°,表明C 1214 -ACDs的润湿性变化优于原料APG1214。最终,在85 g/L NaCl和10 g/L CaCl 2存在下, C 1214 -ACDs的驱油效率为16.6% 。因此,ACD作为超小尺寸的耐温、耐盐纳米颗粒,在高温高盐油藏提高采收率方面具有广阔的应用前景。

更新日期:2024-04-05
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