Herein, we describe our efforts culminating in the total syntheses of discoipyrroles A, B, and C in 6, 6, and 7 steps respectively with excellent overall yield. Total syntheses of these unique natural products have been accomplished involving microwave-mediated Paal–Knorr pyrrole synthesis, Pd-catalyzed carbonylative transformation, and MoOPH (Vedejs reagent) oxidation as key reactions to construct the 1,2,3,5-tetrasubstituted pyrrole and oxidative cyclization of highly substituted pyrrole as key steps.

中文翻译：

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三种海洋天然产物二吡咯 A、B、C 的全合成

在此，我们描述了我们的努力，最终分别通过 6、6 和 7 步全合成二吡咯 A、B 和 C，并具有优异的总产率。这些独特的天然产物的全合成已经完成，涉及微波介导的Paal-Knorr吡咯合成、Pd催化的羰基化转化和MoOPH（Vedejs试剂）氧化作为构建1,2,3,5-四取代吡咯和高取代吡咯的氧化环化是关键步骤。