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Unlocking single molecule magnetism: a supramolecular strategy for isolating neutral MnIII salen-type dimer in crystalline environments
Dalton Transactions ( IF 4 ) Pub Date : 2024-04-03 , DOI: 10.1039/d4dt00323c Yuri Kyoya 1 , Kiyonori Takahashi 1, 2 , Wataru Kosaka 3 , Rui-Kang Huang 1, 2 , Chen Xue 1, 2 , Jia-bing Wu 1, 2 , Hitoshi Miyasaka 3 , Takayoshi Nakamura 1, 2
Dalton Transactions ( IF 4 ) Pub Date : 2024-04-03 , DOI: 10.1039/d4dt00323c Yuri Kyoya 1 , Kiyonori Takahashi 1, 2 , Wataru Kosaka 3 , Rui-Kang Huang 1, 2 , Chen Xue 1, 2 , Jia-bing Wu 1, 2 , Hitoshi Miyasaka 3 , Takayoshi Nakamura 1, 2
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In [Mn(5-MeOsalen)(Cl)]2(dibenzo[24]crown-8), dibenzo[24]crown-8 formed a supramolecule via multi-point interactions with the [Mn(5-MeOsalen)(Cl)] dimer. The dimer was magnetically isolated with ST = 4 and weak interdimer magnetic interactions. The crystal exhibited single-molecule magnet behaviour with an anisotropic barrier of 26(1) K, which is the highest among the Mn-salen series reported to date.
中文翻译：
解锁单分子磁性：在晶体环境中分离中性 MnIII salen 型二聚体的超分子策略
在[Mn(5-MeOsalen)(Cl)] 2 (二苯并[24]crown-8)中，二苯并[24]crown-8通过与[Mn(5-MeOsalen)(Cl)的多点相互作用形成超分子] 二聚体。二聚体被磁隔离，S T = 4 且二聚体间磁相互作用较弱。该晶体表现出单分子磁体行为，各向异性势垒为 26(1) K，是迄今为止报道的 Mn-salen 系列中最高的。
更新日期：2024-04-03
中文翻译：
解锁单分子磁性：在晶体环境中分离中性 MnIII salen 型二聚体的超分子策略
在[Mn(5-MeOsalen)(Cl)] 2 (二苯并[24]crown-8)中，二苯并[24]crown-8通过与[Mn(5-MeOsalen)(Cl)的多点相互作用形成超分子] 二聚体。二聚体被磁隔离，S T = 4 且二聚体间磁相互作用较弱。该晶体表现出单分子磁体行为，各向异性势垒为 26(1) K，是迄今为止报道的 Mn-salen 系列中最高的。
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