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Portable multifunctional sensing platform for ratiometric H2O2 detection and photodynamic anti-bacteria using an AIE-featured electrospinning film
Chemical Engineering Journal ( IF 15.1 ) Pub Date : 2024-03-24 , DOI: 10.1016/j.cej.2024.150675
Xiaofan An , Yuhong Liu , Yunxue Sun , Xuetao Zhang , Yuhua Liu , Yuanyuan Tao , Longsuo Guo , Xiaoping Jiang , Meng Gao

The development of portable flexible sensors for sensitive gas detection with antibacterial activity is of great significance for protecting human health and environment safety. In this paper, we designed a ratiometric sensing platform (PLA@RPEG@TBSN) for reliable and visual monitoring of gaseous HO by electrospinning technology, which reveals self-antibacterial function and highly photostability simultaneously. By employing the aggregation-induced emission (AIE) active nanoparticles (TBSN) as fluorescent responder and Rose Bengal modified photosensitive polymer (RPEG) as reference unit, accurate ratiometric sensing process of PLA@RPEG@TBSN film was realized based on the specific peroxide-mediated reaction between TBSN and HO. The flexible film system demonstrated superiorsensingperformance toward HO vapor, including excellent selectivity, visualized color change and low detection limit (7 ppb). Additionally, benefitting from the photodynamic activity of RPEG, the PLA@RPEG@TBSN film exhibited highly effective antibacterial performance (killing 84 % of bacteria). Moreover, the multifunctional wearable potential is supported by employing film sensor onto the protective mask, which reveals dual capabilities of ratio sensing and resistance bacteria aerosols, encouraging the application of the sensor in complex practical scenario.

中文翻译:

使用具有 AIE 功能的静电纺丝薄膜进行比率式 H2O2 检测和光动力抗菌的便携式多功能传感平台

开发具有抗菌活性的灵敏气体检测的便携式柔性传感器对于保护人类健康和环境安全具有重要意义。在本文中,我们设计了一种比例传感平台(PLA@RPEG@TBSN),通过静电纺丝技术可靠地、可视化地监测气态H2O,该平台同时具有自抗菌功能和高度的光稳定性。采用聚集诱导发射(AIE)活性纳米粒子(TBSN)作为荧光响应体,玫瑰红改性光敏聚合物(RPEG)作为参考单元,基于特定的过氧化物-实现了PLA@RPEG@TBSN薄膜的精确比例传感过程。 TBSN 和 H2O 之间介导的反应。柔性薄膜系统对 H2O 蒸气表现出卓越的传感性能,包括出色的选择性、可视化的颜色变化和低检测限 (7 ppb)。此外,受益于RPEG的光动力活性,PLA@RPEG@TBSN薄膜表现出高效的抗菌性能(杀死84%的细菌)。此外,通过在防护口罩上采用薄膜传感器来支持多功能可穿戴潜力,展现出比率传感和抵抗细菌气溶胶的双重能力,鼓励传感器在复杂的实际场景中的应用。
更新日期:2024-03-24
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