Gold-Catalyzed Cascade Cycloisomerization of 3-Allyloxy-1,6-diynes to Cyclopropyl- and Cyclobutyl-Fused Benzofurans and Chromen-3a(1H)-ols,Organic Letters

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Gold-Catalyzed Cascade Cycloisomerization of 3-Allyloxy-1,6-diynes to Cyclopropyl- and Cyclobutyl-Fused Benzofurans and Chromen-3a(1H)-ols
Organic Letters ( IF 5.2 ) Pub Date : 2024-03-25 , DOI: 10.1021/acs.orglett.4c00705
Zeliang Wang ₁ , Jichao Chen ₁ , Lei Yu ₂ , Chunyu Zhang ₁ , Weidong Rao ₁ , Philip Wai Hong Chan ₂

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A synthetic method for the efficient preparation of partially hydrogenated benzo[f]cyclobuta[cd]cyclopenta[h]benzofurans and cyclopropa[c]chromen-3a(1H)-ols that relies on the gold(I)-catalyzed cascade cycloisomerization of 3-allyloxy-1,6-diynes is described.

中文翻译：

金催化 3-烯丙氧基-1,6-二炔级联环异构化为环丙基和环丁基稠合苯并呋喃和 Chromen-3a(1H)-醇

一种依赖金(I)催化的级联环异构化高效制备部分氢化苯并[ f ]环丁[ cd ]环戊[ h ]苯并呋喃和环丙[ c ]色烯-3a(1H ) -醇的合成方法描述了3-烯丙氧基-1,6-二炔。

更新日期：2024-03-25

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