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Tailoring Cu immobilized MCM-41-based mesostructured catalysts for selective hydrogenolysis of biomass-derived furfural
Catalysis Communications ( IF 3.7 ) Pub Date : 2024-03-07 , DOI: 10.1016/j.catcom.2024.106898
Leela Prasad Yandrati , Swamy Sekhar Kaladi , Raveendra Gundeboyina , Ramakrishna Pothu , Vijaya Moli , B. Venkateswara Rao , Rajender Boddula , Rammohanrao Devulapalli , Harisekhar Mitta

The CuO-supported MCM-41 catalysts were prepared using a simple incipient wet impregnation method. The catalysts were investigated for hydrogenation of furfural to furfuryl alcohol synthesis. Among all the catalysts, the 2.5% CuO/MCM-41 catalyst shows the best catalytic performance with 92.5% conversion and 89% selectivity of furfuryl alcohol at 210 °C. The catalyst also demonstrated a high turnover frequency (TOF) of 154.4 h. The 2.5% CuO/MCM-41 catalyst remained stable for up to 20 h during the time on stream.

中文翻译:

定制铜固定MCM-41介孔结构催化剂用于生物质糠醛的选择性氢解

采用简单的初湿浸渍法制备了 CuO 负载的 MCM-41 催化剂。研究了该催化剂用于糠醛加氢合成糠醇的情况。在所有催化剂中,2.5%CuO/MCM-41催化剂表现出最好的催化性能,在210℃下,糠醇的转化率为92.5%,糠醇选择性为89%。该催化剂还表现出 154.4 小时的高周转频率 (TOF)。 2.5% CuO/MCM-41 催化剂在运行期间可保持稳定长达 20 小时。
更新日期:2024-03-07
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