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Hierarchical Transparent Back Contacts for Bifacial CdTe PV
ACS Energy Letters ( IF 22.0 ) Pub Date : 2024-03-20 , DOI: 10.1021/acsenergylett.4c00156
B. Edward Sartor 1, 2 , Teng Zhang 3 , Christopher P. Muzzillo 2 , Chungho Lee 4 , Ryan Muzzio 2 , Yury Gogotsi 3 , Matthew O. Reese 2 , André D. Taylor 1
Affiliation  

A hierarchical transparent back contact leveraging an AlGaOx passivating layer, Ti3C2Tx MXene with a high work function, and a transparent cracked film lithography (CFL) templated nanogrid is demonstrated on copper-free cadmium telluride (CdTe) devices. AlGaOx improves device open-circuit voltage but reduces the fill factor when using a CFL-templated metal contact. Including a Ti3C2Tx interlayer improves the fill factor, lowers detrimental Schottky barriers, and enables metallization with CFL by providing transverse conduction into the nanogrid. The bifacial performance of an AlGaOx/Ti3C2Tx/CFL gold contact is evaluated, reaching 19.5% frontside efficiency and 2.8% backside efficiency under 1-sun illumination for a copper-free, group-V doped CdTe device. Under dual illumination, device power generation reached 200 W/m2 with 0.1 sun backside illumination.

中文翻译:

用于双面 CdTe PV 的分层透明背接触

在无铜碲化镉 (CdTe) 器件上演示了利用 AlGaO x钝化层、具有高功函数的 Ti 3 C 2 T x MXene 和透明裂纹薄膜光刻 (CFL) 模板纳米网格的分层透明背接触。当使用 CFL 模板金属接触时, AlGaO x可以提高器件开路电压,但会降低填充因子。包含 Ti 3 C 2 T x中间层可提高填充因子,降低有害的肖特基势垒,并通过向纳米网格提供横向传导来实现 CFL 金属化。评估了 AlGaO x /Ti 3 C 2 T x /CFL 金触点的双面性能,在 1 太阳光照下,无铜、V 族掺杂的 CdTe 器件的正面效率达到 19.5%,背面效率达到 2.8%。双光照下, 0.1太阳光背面光照下,器件发电量达到200 W/m 2 。
更新日期:2024-03-20
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