Pd-Catalyzed Enantioselective Creation of All-Carbon Quaternary Center with 2,3-Allenylic Carbonates,Organic Letters

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Pd-Catalyzed Enantioselective Creation of All-Carbon Quaternary Center with 2,3-Allenylic Carbonates
Organic Letters ( IF 4.9 ) Pub Date : 2024-03-15 , DOI: 10.1021/acs.orglett.2c02497
Jie Lin ₁ , Minqiang Jia ₁ , Xu Song ₁ , Hao Yu ₁ , Shengming Ma _{1,

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Affiliation

Enantioselective construction of all-carbon quaternary centers has been achieved via the palladium-catalyzed highly enantioselective allenylation of oxindoles with 2,3-allenylic carbonates to afford a variety of optically active allene products, which contain oxindole units with different functional groups, in high ee. The corresponding synthetic applications have also been demonstrated.

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