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Improved access to polythioesters by heterobimetallic aluminium catalysis
Chemical Communications ( IF 4.9 ) Pub Date : 2024-03-13 , DOI: 10.1039/d4cc00811a
Bhargav R. Manjunatha 1 , Merlin R. Stühler 2 , Luise Quick 2 , Alex J. Plajer 1
Affiliation  

Bimetallic Al(III) catalysis mediates thioanhydride/epoxide copolymerisation at greatly improved rates and monomer tolerance than analogous Cr(III) catalysis. Moving to sulfurated monomers furthermore generally improves rates and selectivites.

中文翻译:

通过异双金属铝催化改善聚硫酯的制备

与类似的 Cr( III ) 催化相比,双金属 Al( III ) 催化以大大提高的速率和单体耐受性介导硫代酸酐/环氧化物共聚。此外,转向硫化单体通常还可以提高速率和选择性。
更新日期:2024-03-18
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