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Lowering the kinetic barrier via enhancing electrophilicity of surface oxygen to boost acidic oxygen evolution reaction
Matter ( IF 18.9 ) Pub Date : 2024-02-14 , DOI: 10.1016/j.matt.2024.01.025
Ning Han , Xuan Zhang , Chi Zhang , Shihui Feng , Wei Zhang , Wei Guo , Runtian Zheng , Renji Zheng , Pengyun Liu , Yu Li , Jan Fransaer , Bao-Lian Su

Tremendous energy is required to break the strong covalent O-H bond of HO in acidic media, resulting in sluggish OER kinetics. Herein, the authors report a one-stone-two-birds strategy to effectively enhance the electrophilicity of surface oxygen, assisting absorption and facilitating dissociation of HO, which essentially leads to ultrahigh OER activity in acidic media.

中文翻译:

通过增强表面氧的亲电性来降低动力学势垒以促进酸性析氧反应

在酸性介质中,需要巨大的能量来破坏 H2O 的强共价 OH 键,导致 OER 动力学缓慢。在此,作者报告了一种一石二鸟的策略,可以有效增强表面氧的亲电性,协助吸收并促进 H2O 的解离,这本质上导致了酸性介质中超高的 OER 活性。
更新日期:2024-02-14
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