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Kirkendall oxidation tailors lattice strain in transition metal oxides for efficient oxygen electrocatalysis
Matter ( IF 18.9 ) Pub Date : 2024-02-05 , DOI: 10.1016/j.matt.2024.01.013
Yinghui Li , Haoming Shen , Buguang Zhou , Junyi Li , Liming Wang , Qiang Sun , Seeram Ramakrishna , Mingchuan Luo , Dongxiao Ji , Xiaohong Qin

The lattice tensile strain of transition metal oxides is precisely regulated through a nanoscale Kirkendall diffusion process, leading to remarkable bifunctional electrocatalytic performances. It facilitates the electron exchange from Co-3d to O-2p, promoting the adsorption of OOH and the desorption of OH, accordingly realizing enhanced oxygen catalytic activity.

中文翻译:

柯肯德尔氧化调整过渡金属氧化物中的晶格应变,以实现高效的氧电催化

通过纳米级柯肯德尔扩散过程精确调节过渡金属氧化物的晶格拉伸应变,从而实现卓越的双功能电催化性能。它促进了Co-3d到O-2p的电子交换,促进OOH的吸附和OH的解吸,从而实现增强的氧催化活性。
更新日期:2024-02-05
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