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Strain tuning MoO3 vibrational and electronic properties
npj 2D Materials and Applications ( IF 9.7 ) Pub Date : 2024-01-24 , DOI: 10.1038/s41699-024-00442-3
Sergio Puebla , Hao Li , Onur Çakıroğlu , Estrella Sánchez-Viso , C. Munuera , Roberto D’Agosta , Andres Castellanos-Gomez

This work investigates the vibrational and electrical properties of molybdenum trioxide (α-MoO3) upon tensile strain applied along different crystal directions. Using a three-point bending setup in combination with Raman spectroscopy, we report measurements of a blueshift of the Raman modes when uniaxial tensile strain is applied along the a- and c-axis to this material. Furthermore, the electrical measurements reveal an increase in resistance with strain applied along both in-plane directions. The findings from the uniaxial strain and Raman spectroscopy measurements are further confirmed by ab-initio calculations. This study provides valuable insights into the mechanical and vibrational properties of α-MoO3 and its potential use in several applications. This study contributes to the growing body of knowledge on the properties of α-MoO3 and lays the foundation for further exploration of its potential applications. Given MoO3 holding the natural hyperbolic phonon polaritons, attracting significant research interest, this study has the potential to arouse the curiosity of the scientific community.



中文翻译:

应变调谐 MoO3 振动和电子特性

这项工作研究了沿不同晶体方向施加拉伸应变时三氧化钼 (α-MoO 3 )的振动和电学特性。使用三点弯曲设置与拉曼光谱相结合,我们报告了当沿 ac轴向该材料施加单轴拉伸应变时拉曼模式蓝移的测量结果。此外,电气测量结果表明,随着沿两个面内方向施加的应变,电阻会增加。单轴应变和拉曼光谱测量的结果通过从头计算得到进一步证实。这项研究为 α-MoO 3的机械和振动特性及其在多种应用中的潜在用途提供了宝贵的见解。这项研究有助于不断丰富关于α-MoO 3性质的知识,并为进一步探索其潜在应用奠定基础。鉴于MoO 3拥有天然的双曲声子极化激元,吸引了人们极大的研究兴趣,这项研究有可能引起科学界的好奇。

更新日期:2024-01-25
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