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FTIR study of nanocrystalline titanium carbide (TiC) particles exposed to gamma radiation
Solid State Communications ( IF 2.1 ) Pub Date : 2023-12-21 , DOI: 10.1016/j.ssc.2023.115417
Elchin M. Huseynov , Raisa R. Hakhiyeva , Nizami M. Mehdiyev

The infrared (IR) spectra of nanocrystalline TiC particles have been compared before and after gamma radiation (5 Mrad, 15 Mrad, 50 Mrad and 150 Mrad) in the 400–4000 cm−1 wavenumber. According to the general approach, the analysis of the spectra has revealed that four sharp peaks appear in the sample before gamma radiation. The value of the wavenumber in TiC nanoparticles, which explains the Ti–C bond, has been determined before and after gamma radiation. Amorphous transformation and other changes in the nanocrystalline TiC particles under the gamma radiation have been explained by FTIR spectroscopy. Simultaneously, the effects of gamma radiation have been explained by wavenumbers corresponding to various spatial oscillations on the surface of nanocrystalline TiC particles. Moreover, the optimized bond structure of TiC nanoparticles and possible bond changes under the gamma radiation are described elaborately in the study.



中文翻译:

暴露于伽马辐射下的纳米晶碳化钛 (TiC) 颗粒的 FTIR 研究

比较了纳米晶 TiC 颗粒在 400–4000 cm -1波数的伽马辐射(5 Mrad、15 Mrad、50 Mrad 和 150 Mrad)前后的红外(IR)光谱。根据一般方法,光谱分析表明,在伽马辐射之前样品中出现了四个尖峰。TiC 纳米粒子的波数值(解释了 Ti-C 键)已在伽马辐射之前和之后确定。FTIR 光谱解释了伽马辐射下纳米晶 TiC 颗粒的非晶转变和其他变化。同时,伽马辐射的影响可以通过与纳米晶 TiC 颗粒表面的各种空间振荡相对应的波数来解释。此外,研究中还详细描述了TiC纳米粒子的优化键结构以及伽马辐射下可能的键变化。

更新日期:2023-12-23
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