Perfluoroalkoxylation reaction via dual concurrent catalysis,Chemical Communications

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Perfluoroalkoxylation reaction via dual concurrent catalysis
Chemical Communications ( IF 4.3 ) Pub Date : 2023-06-09 , DOI: 10.1039/d3cc02485g
Shota Fujioka ₁ , Keiichi Hirano ₁ , Naoyuki Hoshiya ₂ , Akiyoshi Yamauchi ₂ , Yosuke Kishikawa ₂ , Masanobu Uchiyama _{1,

3}

Affiliation

A catalytic amount of CsI enables dual concurrent activation of poorly reactive perfluoroalkoxide and alkyl halides, especially alkyl chlorides, leading to the formation of diverse perfluoroalkoxylated organic compounds. Installation of perfluoroalkoxy groups by this methodology is cost-effective, circumventing the need for over-stoichiometric cesium or silver salts. This methodology also provides high functional group compatibility and tolerance of sterically hindered substrates.

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