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Nickel-Catalyzed Markovnikov-Selective Hydrodifluoromethylation of Alkynes Using BrCF2H
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-06-09 , DOI: 10.1002/anie.202305426
Shiwei Pan 1 , Fan Chen 1 , Yanyan Zhang 1 , Liang Shao 1 , Lingling Chu 1
Affiliation  

A Markovnikov-selective hydrodifluoromethylation of alkynes with BrCF2H via nickel catalysis is described, enabling straightforward access to diverse branched CF2H-alkenes with high efficiency and excellent regioselectivity.

中文翻译:

使用 BrCF2H 进行镍催化马尔可夫尼科夫选择性炔烃氢二氟甲基化

描述了通过镍催化用 BrCF 2 H对炔烃进行马尔可夫尼科夫选择性氢二氟甲基化,从而能够以高效率和优异的区域选择性直接获得多种支链 CF 2 H-烯烃。
更新日期:2023-06-09
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