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Anthracene-Porphyrin Nanoribbons
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-06-09 , DOI: 10.1002/anie.202307035
He Zhu 1 , Qiang Chen 1 , Igor Rončević 1, 2 , Kirsten E Christensen 1 , Harry L Anderson 1
Affiliation  

Porphyrin dimer and trimer oligomers were synthesized by fusing porphyrin and anthracene units in an edge-to-edge manner. Efficient intramolecular π-delocalization is demonstrated by absorption spectra extending far into the near-IR and by high redox activity. This is a promising strategy for incorporating metal ions into a 1D semiconductor through solution-phase synthesis.

中文翻译:

蒽-卟啉纳米带

通过以边对边的方式融合卟啉和蒽单元来合成卟啉二聚体和三聚体寡聚物。吸收光谱延伸至近红外区域并具有高氧化还原活性,证明了有效的分子内 π 离域作用。这是通过溶液相合成将金属离子掺入一维半导体的一种有前景的策略。
更新日期:2023-06-09
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