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Modulating Electronic Metal-Support Interactions to Boost Visible-Light-Driven Hydrolysis of Ammonia Borane: Nickel-Platinum Nanoparticles Supported on Phosphorus-Doped Titania
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2023-06-08 , DOI: 10.1002/anie.202305371 Chao Wan 1, 2, 3 , Gui Li 3 , Jiapei Wang 3 , Lixin Xu 3 , Dang-Guo Cheng 1 , Fengqiu Chen 1 , Yusuke Asakura 4 , Yunqing Kang 2 , Yusuke Yamauchi 4, 5
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2023-06-08 , DOI: 10.1002/anie.202305371 Chao Wan 1, 2, 3 , Gui Li 3 , Jiapei Wang 3 , Lixin Xu 3 , Dang-Guo Cheng 1 , Fengqiu Chen 1 , Yusuke Asakura 4 , Yunqing Kang 2 , Yusuke Yamauchi 4, 5
Affiliation
Ni−Pt nanoparticles supported on P-doped TiO2 mediate visible-light-driven ammonia borane hydrolysis. The optimized Ni40Pt60/P-TiO2 catalyst exhibits a high turnover frequency of 967.8 molH2 molPt−1 min−1. P doping enhances the visible-light absorption and modulates the electronic states of the metals to enhance the strong metal-support interactions, thereby promoting the hydrogen-evolving activity and stability of the catalyst.
中文翻译:
调节电子金属载体相互作用以促进可见光驱动的氨硼烷水解:磷掺杂二氧化钛负载的镍铂纳米粒子
P 掺杂 TiO 2上负载的 Ni−Pt 纳米粒子介导可见光驱动的氨硼烷水解。优化的Ni 40 Pt 60 /P-TiO 2催化剂表现出967.8 mol H2 mol Pt -1 min -1的高周转频率。P掺杂增强可见光吸收并调节金属的电子态,增强金属-载体的强相互作用,从而促进催化剂的析氢活性和稳定性。
更新日期:2023-06-08
中文翻译:
调节电子金属载体相互作用以促进可见光驱动的氨硼烷水解:磷掺杂二氧化钛负载的镍铂纳米粒子
P 掺杂 TiO 2上负载的 Ni−Pt 纳米粒子介导可见光驱动的氨硼烷水解。优化的Ni 40 Pt 60 /P-TiO 2催化剂表现出967.8 mol H2 mol Pt -1 min -1的高周转频率。P掺杂增强可见光吸收并调节金属的电子态,增强金属-载体的强相互作用,从而促进催化剂的析氢活性和稳定性。