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Directional and Ultrafast Charge Transfer in Oxygen-Vacancy-Rich ZnO@Single-Atom Cobalt Core-Shell Junction for Photo-Fenton-Like Reaction
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2023-05-30 , DOI: 10.1002/anie.202305639
Xi-Lin Wu 1 , Shiang Liu 1 , Yu Li 1 , Minjia Yan 1 , Hongjun Lin 1 , Jianrong Chen 1 , Shoujie Liu 2 , Shaobin Wang 3 , Xiaoguang Duan 3
Affiliation  

Photocatalyst/single-atom catalysts core–shell heterojunctions were constructed. The strong built-in electric field across the heterojunction promotes charge separation and migration. Photogenerated electrons could rapidly (2 ps) transfer from the ZnO “core” to the single-atom Co catalysts “shell”, boosting the catalytic performance for heterogeneous photo-Fenton-like reaction.

中文翻译:

富氧空位 ZnO@单原子钴核壳结中的定向和超快电荷转移用于类 Fenton 反应

构建了光催化剂/单原子催化剂核壳异质结。异质结上强大的内置电场促进电荷分离和迁移。光生电子可以快速(2 ps)从ZnO“核”转移到单原子Co催化剂“壳”,从而提高非均相光芬顿反应的催化性能。
更新日期:2023-05-30
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