Molecular Exclusion Separation of 1-Butene Isomers by a Robust Metal–Organic Framework under Humid Conditions,Angewandte Chemie International Edition

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Molecular Exclusion Separation of 1-Butene Isomers by a Robust Metal–Organic Framework under Humid Conditions
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-05-31 , DOI: 10.1002/anie.202303671
Xin Huang ₁ , Shuyi Jiang ₁ , Dou Ma ₁ , Jing Xie ₁ , Xiao Feng ₁ , Bo Wang ₁

Affiliation

With tailored pore environments, ultramicroporous MOF (MET-Fe) realized the molecular exclusion separation of 1-butene isomers. High-purity isobutene was obtained directly from a gas mixture, and large amounts of n-butene were collected in a mild regeneration process. Moreover, the high robustness endowed the adsorbent with excellent durability and unaffected separation performance in humidity.

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