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Structure and functional properties of oxides in the BaO–Al2O3 system: Phosphors, pigments and catalysts
Progress in Solid State Chemistry ( IF 12.0 ) Pub Date : 2022-10-28 , DOI: 10.1016/j.progsolidstchem.2022.100379
Zhiwei Wang , Yuqian Wang , M.A. Subramanian , Peng Jiang

Oxides such as BaAl12O19 and BaAl2O4 in the BaO–Al2O3 system demonstrate potential for optical applications due to the abundant tetrahedral and octahedral sites in their structures, as well as their high thermal stability, good chemical stability, high surface area and strong light absorption capacity. Rare earth element doping or transition metal ion doping in oxides in the BaO–Al2O3 system contributes to promising photoluminescent, visible color and catalytic properties. In this review, the structures of BaAl12O19, BaAl2O4, Ba3Al2O6, Ba4Al2O7, and Ba7Al2O10 in the BaO–Al2O3 system are introduced. Their applications in phosphors, pigments and catalysts are also summarized herein.



中文翻译:

BaO–Al2O3 体系中氧化物的结构和功能特性:荧光粉、颜料和催化剂

BaO-Al 2 O 3体系中的BaAl 12 O 19和BaAl 2 O 4等氧化物因其结构中丰富的四面体和八面体位点以及热稳定性高、化学稳定性好、比表面积大,吸光能力强。在 BaO–Al 2 O 3体系的氧化物中掺杂稀土元素或过渡金属离子有助于提高光致发光、可见颜色和催化性能。在这篇综述中,BaAl 12 O 19 , BaAl 2 O 4 , Ba的结构介绍了BaO-Al 2 O 3体系中的3 Al 2 O 6、Ba 4 Al 2 O 7和Ba 7 Al 2 O 10 。本文还总结了它们在荧光粉、颜料和催化剂中的应用。

更新日期:2022-10-28
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