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Equilibrium between 4-acetoxypyridine and N-acetyl-4-pyridone; a correction of the literature
J. Chem. Soc. C Pub Date : 1970 , DOI: 10.1039/j39700002426
Ian Fleming , D. Philippides

The known compound, reported in the literature to be 4-acetoxypyridine, is shown to be N-acetyl-4-pyridone. In solution the two isomers are in equilibrium. 4-Pyridone is acetylated by acetic anhydride more rapidly and more completely than is 2-pyridone.

中文翻译:

4-乙酰氧基吡啶和N-乙酰基-4-吡啶酮之间的平衡;改正文学

文献中报道为4-乙酰氧基吡啶的已知化合物显示为N-乙酰基-4-吡啶酮。在溶液中,两种异构体处于平衡状态。与2-吡啶酮相比,4-吡啶酮被乙酸酐乙酰化的速度更快,更完全。
更新日期:2017-01-31
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