Tamao–Fleming oxidation of the N-dimethylphenylsilylmethyl group linked to the nitrogen of a peptide bond enables access to dipeptide N,O-acetal functionality. The N-silylmethyl functionality serves as a latent form of the N,O-acetal which is revealed after peptide bond construction.

中文翻译：

---

带有N，O-缩醛官能度的二肽的Tamao-Fleming氧化途径

与肽键氮相连的N-二甲基苯基甲硅烷基甲基的Tamao-Fleming氧化使得能够使用二肽N，O-缩醛官能团。所述Ñ -silylmethyl功能作为一个潜在形式N，O，其肽键施工后显露-acetal。