Synthesis of an F-BODIPY [2]catenane using the chemistry of bis(dipyrrinato)metal complexes,Chemical Communications

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Synthesis of an F-BODIPY [2]catenane using the chemistry of bis(dipyrrinato)metal complexes
Chemical Communications ( IF 4.3 ) Pub Date : 2017-10-16 00:00:00 , DOI: 10.1039/c7cc07021g
Bilal Nisanci _{1,

2,

3,

4,

5} , Sinem Sahinoglu _{1,

2,

3,

4,

5} , Esra Tuner _{1,

2,

3,

4,

5} , Mustafa Arik _{1,

2,

3,

4,

5} , İbrahim Kani _{1,

5,

6,

7} , Arif Dastan _{1,

2,

3,

4,

5} , Özgür Altan Bozdemir _{1,

2,

3,

4,

5}

Affiliation

ML₂ type complexes of an olefin terminated 5H-dipyrrin ligand can be subjected to twofold ring closing metathesis to give bis(dipyrrinato)copper(II) and bis(dipyrrinato)zinc(II) [2]catenates. Demetalation of the copper(II) [2]catenate with KCN/N₂H₄·H₂O gave the corresponding bis(dipyrrin) [2]catenand. The boron difluoride complex of this bis(dipyrrin) was obtained as the first fluorescent F-BODIPY [2]catenane.

中文翻译：

利用双（双吡啶）金属配合物的化学合成F-BODIPY [2]环戊烷

可以将烯烃封端的5 H- dipyrrin配体的ML ₂型配合物进行双环闭环置换，以生成双（dipyrrinato）铜（II）和双（dipyrrinato）锌（II）[2]酸酯。用KCN / N ₂ H ₄ ·H ₂ O对铜（II）[2] catenate进行脱金属，得到相应的双（联吡啶）[2] catenand。获得该双（联吡啶）的二氟化硼配合物，作为第一荧光F-BODIPY [2]联烷。

更新日期：2017-11-16

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