The active site for the water oxidising anodic iridium oxide probed through in situ Raman spectroscopy,Chemical Communications

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The active site for the water oxidising anodic iridium oxide probed through in situ Raman spectroscopy
Chemical Communications ( IF 4.3 ) Pub Date : 2017-10-09 00:00:00 , DOI: 10.1039/c7cc05669a
Zoran Pavlovic _{1,

2,

3,

4,

5} , Chinmoy Ranjan _{1,

2,

3,

4,

5} , Maurice van Gastel _{1,

2,

3,

4,

5} , Robert Schlögl _{1,

2,

3,

4,

5}

Affiliation

The structure of anodic iridium oxide (IrO_x) under water oxidation was explored using in situ Raman spectroscopy and theoretical calculations. Isotopic substitution experiments and theoretical calculations confirmed formation of an Ir [double bond, length as m-dash]