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Synthesis of Tetra(3-thienyl)biphenoquinone and its Charge Transfer Complex with Perylene
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2017-11-16 09:20:28 , DOI: 10.1002/ajoc.201700560
Ryotaro Fujii 1 , Md. Awlad Hossain 1 , Hisato Akimoto 1 , Kazunori Hirabayashi 1 , Toshio Shimizu 1 , Kazuhiko Akiyama 1 , Kenta Goto 2 , Hiroyuki Nishikawa 3 , Ken-ichi Yamashita 4 , Ken-ichi Sugiura 1
Affiliation  

Tetra(3-thienyl)biphenoquinone was designed and prepared. In contrast to reported aryl-substituted biphenoquinones, the title compound takes a nearly planar structure. This resulted in good conjugation in the entire molecule and the formation of a charge transfer complex with perylene in the solid state.

中文翻译:

四(3-噻吩基)联苯醌的合成及其与Per的电荷转移配合物

设计并制备了四(3-噻吩基)联苯醌。与报道的芳基取代的联苯醌相比,标题化合物具有接近平面的结构。这导致了整个分子的良好结合,并形成了与固态charge的电荷转移络合物。
更新日期:2017-11-16
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