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Photocatalyst-free, Visible Light Driven, Gold Promoted Suzuki Synthesis of (Hetero)biaryls
ChemCatChem ( IF 3.8 ) Pub Date : 2017-11-14 12:36:07 , DOI: 10.1002/cctc.201701436
Christopher Sauer 1 , Yang Liu 1 , Assunta De Nisi 1 , Stefano Protti 2 , Maurizio Fagnoni 2 , Marco Bandini 1
Affiliation  

So free, so good. A version of Suzuki cross-coupling is realized by merging visible photoredox catalysis and [AuI] catalysis. The employment of colored and photolabile arylazosulfone as reaction partners enables the biaryl forming protocol to be performed under photocatalyst-free conditions.

中文翻译:

不含光催化剂,可见光驱动,金促进的(杂)联芳基的铃木合成

如此 自由,如此美好。通过合并可见光氧化还原催化和[Au I ]催化,可以实现Suzuki交叉偶联的一种形式。通过使用有色和不稳定的芳基偶氮砜作为反应伙伴,可以在无光催化剂的条件下进行联芳基形成方案。
更新日期:2017-11-15
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