Hydrogen Peroxide Assisted Selective Oxidation of 5-Hydroxymethylfurfural in Water under Mild Conditions,ChemCatChem

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Hydrogen Peroxide Assisted Selective Oxidation of 5-Hydroxymethylfurfural in Water under Mild Conditions
ChemCatChem ( IF 3.8 ) Pub Date : 2017-11-14 12:35:29 , DOI: 10.1002/cctc.201701302
Ching-Tien Chen,Chi Van Nguyen,Zheng-Yen Wang,Yoshio Bando,Yusuke Yamauchi,Manar Tareq Saleh Bazziz,Amanullah Fatehmulla,W. Aslam Farooq,Takuya Yoshikawa,Takao Masuda,Kevin C.-W. Wu

Things that make you go HMF: We propose an effective liquid-phase oxidation system for the selective oxidation of 5-hydroxymethylfurfural (HMF) to either 5-formyl-2-furoic acid (FFCA) or 2,5-furandicarboxylic acid (FDCA) in high yield by using activated carbon supported ruthenium (Ru/AC) and H₂O₂ as the catalyst and oxidant, respectively.

中文翻译：

轻度条件下水中的过氧化氢辅助选择性氧化5-羟甲基糠醛

使您变得HMF的事情：我们提出了一种有效的液相氧化系统，用于将5-羟甲基糠醛（HMF）选择性氧化为5-甲酰基-2-糠酸（FFCA）或2,5-呋喃二甲酸（FDCA）通过使用活性炭负载的钌（Ru / AC）和H ₂ O _2分别作为催化剂和氧化剂，可以实现高收率。

更新日期：2017-11-15

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