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Photocatalytic Decomposition of RhB by Newly Designed and Highly Effective [email protected]/CdS Hierarchical Heterostructures
ACS Sustainable Chemistry & Engineering ( IF 8.4 ) Pub Date : 2017-11-22 00:00:00 , DOI: 10.1021/acssuschemeng.7b02005
Z.J. Yu 1 , M. Rajesh Kumar 1, 2 , Y. Chu 1 , H.X. Hao 1 , Q.Y. Wu 1 , H.D. Xie 1
Affiliation  

A two-step hydrothermal method was developed to produce CdS nanoparticle–sensitized ZnO nanoneedle heterostructures, which array on copper fiber (CF), and its applications in the field of photocatalysts were also explored. In this novel heterostructure, the CF plays a role in supporting the carriers of CdS nanoparticles–sensitized ZnO nanoneedles. Furthermore, CF is capable of accelerating the exportation of charge carriers. Therefore, [email protected]/CdS hierarchical heterostructures present excellent photocatalytic performance under visible light, enabling the decomposition of organic dyes such as RhB within 60 min, with desirable cycling ability. Because of the sustainability and engineering potential of CF in chemistry, it is easy for it to be recycled. This method we developed also conformed to the development of green chemistry without using organic solvents in the entire fabrication process of [email protected]/CdS hierarchical heterostructures. This work may pave the way for a useful system to realize efficient charge separation and transmission, which could exert significant influence on the large-scale synthesis of photocatalytic materials with low cost and enhanced performance.

中文翻译:

新型设计和高效[受电子邮件保护] / CdS分层异质结构对RhB的光催化分解

开发了一种两步水热法来制备CdS纳米颗粒致敏的ZnO纳米针异质结构,该结构排列在铜纤维(CF)上,并探索了其在光催化剂领域的应用。在这种新颖的异质结构中,CF在支持CdS纳米颗粒致敏的ZnO纳米针的载体中发挥了作用。此外,CF能够加速电荷载流子的输出。因此,[电子邮件保护] / CdS分层异质结构在可见光下具有出色的光催化性能,能够在60分钟内分解有机染料,例如RhB,并具有理想的循环能力。由于CF在化学方面的可持续性和工程潜力,因此很容易对其进行回收。我们开发的这种方法还符合绿色化学的发展,在[电子邮件保护] / CdS分层异质结构的整个制造过程中不使用有机溶剂。这项工作可以为有用的系统实现高效的电荷分离和传输铺平道路,这可能以低成本和增强的性能对光催化材料的大规模合成产生重大影响。
更新日期:2017-11-22
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