Photochemical and oxidative cyclisation of tetraphenylpyrroles,Organic & Biomolecular Chemistry

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Photochemical and oxidative cyclisation of tetraphenylpyrroles
Organic & Biomolecular Chemistry ( IF 2.9 ) Pub Date : 2017-10-25 00:00:00 , DOI: 10.1039/c7ob02537h
Jayne L. Ferguson _{1,

2,

3,

4} , Marie A. Squire _{1,

2,

3,

4} , Christopher M. Fitchett _{1,

2,

3,

4}

Affiliation

The photochemical and oxidative cyclodehydrogenation reactions of tetraphenylpyrroles act in a complementary fashion for the cyclisation of N-ethyl and N-benzyl derivatives. In the case of the former, a doubly cyclised product was isolated from cyclisation with solid FeCl₃, while the latter gives a rearranged 3H-pyrrole upon irradiation.

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