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Iridium(III)-catalysed cross-linking of polysiloxanes leading to the thermally resistant luminescent silicone rubbers
Catalysis Science & Technology ( IF 4.4 ) Pub Date : 2017-11-01 00:00:00 , DOI: 10.1039/c7cy02013a Regina M. Islamova 1, 2, 3, 4 , Mikhail V. Dobrynin 1, 2, 3, 4 , Andrey V. Vlasov 1, 2, 3, 4 , Anzhelika A. Eremina 1, 2, 3, 4 , Mikhail A. Kinzhalov 1, 2, 3, 4 , Ilya E. Kolesnikov 1, 2, 3, 4 , Andrey A. Zolotarev 1, 2, 3, 4 , Eleonora A. Masloborodova 5, 6, 7 , Konstantin V. Luzyanin 1, 2, 3, 4, 8
Catalysis Science & Technology ( IF 4.4 ) Pub Date : 2017-11-01 00:00:00 , DOI: 10.1039/c7cy02013a Regina M. Islamova 1, 2, 3, 4 , Mikhail V. Dobrynin 1, 2, 3, 4 , Andrey V. Vlasov 1, 2, 3, 4 , Anzhelika A. Eremina 1, 2, 3, 4 , Mikhail A. Kinzhalov 1, 2, 3, 4 , Ilya E. Kolesnikov 1, 2, 3, 4 , Andrey A. Zolotarev 1, 2, 3, 4 , Eleonora A. Masloborodova 5, 6, 7 , Konstantin V. Luzyanin 1, 2, 3, 4, 8
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Cyclometallated iridium(III) complexes with 2-phenylpyridine [Ir(ppy)2(CNR)Cl] (ppy = (2-phenylpyridinato-C2,N), R = Xyl, Mes), [Ir(ppy)2(CNR)2](OTf) (R = Xyl, Mes), and fac-[Ir(ppy)3] catalyse the cross-linking of polysiloxanes exclusively at temperatures above 100 °C leading to luminescent rubbers.
中文翻译：
铱（III）催化的聚硅氧烷交联，产生耐热的发光硅橡胶
环金属化铱（III）与2-苯基吡啶[Ir（ppy）2（CNR）Cl]的配合物（ppy =（2-苯基吡啶基-C 2，N），R = Xyl，Mes），[Ir（ppy）2（CNR ）2 ]（OTf）（R = Xyl，Mes）和fac- [Ir（ppy）3 ]仅在高于100°C的温度下催化聚硅氧烷的交联，从而产生发光橡胶。
更新日期：2017-11-15
中文翻译：
铱（III）催化的聚硅氧烷交联，产生耐热的发光硅橡胶
环金属化铱（III）与2-苯基吡啶[Ir（ppy）2（CNR）Cl]的配合物（ppy =（2-苯基吡啶基-C 2，N），R = Xyl，Mes），[Ir（ppy）2（CNR ）2 ]（OTf）（R = Xyl，Mes）和fac- [Ir（ppy）3 ]仅在高于100°C的温度下催化聚硅氧烷的交联，从而产生发光橡胶。
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