Gold-catalyzed [2+2+2+2]-annulation of 1,3,5-hexahydro-1,3,5-triazines with alkoxyallenes,Chemical Communications

当前位置： X-MOL 学术 › Chem. Commun. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Gold-catalyzed [2+2+2+2]-annulation of 1,3,5-hexahydro-1,3,5-triazines with alkoxyallenes
Chemical Communications ( IF 4.3 ) Pub Date : 2017-11-08 00:00:00 , DOI: 10.1039/c7cc07554e
Shiyong Peng _{1,

2,

3,

4,

5} , Danqing Ji _{1,

2,

3,

4,

5} , Jiangtao Sun _{1,

2,

3,

4,

5}

Affiliation

An unprecedented gold-catalyzed [2+2+2+2]-annulation of 1,3,5-hexahydro-1,3,5-triazines with alkoxyallenes has been developed, providing eight-membered heterocycles in good to excellent yields. Deuterium labeling and control experiments reveal the possible reaction mechanism for this annulation.

中文翻译：

金催化1,3,5-六氢-1,3,5-三嗪与烷氧基丙烯烯的[2 + 2 + 2 + 2]-环化

已经开发了前所未有的金催化的1,3,5-六氢-1,3,5-三嗪与烷氧基丙烯烯的[2 + 2 + 2 + 2]环化反应，提供了八元杂环，收率好至极佳。氘标记和对照实验揭示了这种环空反应的可能反应机理。

更新日期：2017-11-15

点击分享查看原文

点击收藏

阅读更多本刊最新论文本刊介绍/投稿指南11