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Cu2+-selective fluorescent probe based on the hydrolysis of semicarbazide derivative of 2-(2-aminophenyl)benzothiazole
Dyes and Pigments ( IF 4.5 ) Pub Date : 2017-11-13 , DOI: 10.1016/j.dyepig.2017.11.022
Hyein Ryu , Myung Gil Choi , Eun Jin Cho , Suk-Kyu Chang

A new Cu2+-selective reaction-based fluorescent probe 1 based on the semicarbazide-bearing derivative of 2-(2-aminophenyl)benzothiazole has been developed. Designed probe 1 exhibited turn-on-type fluorescence signaling behavior that was more prominent toward Cu2+ ions than to other environmentally relevant metal ions. The signaling of probe 1 was due to the Cu2+-induced hydrolysis of semicarbazide moiety to form its strongly fluorescent parent dye. Cu2+ signaling of probe 1 was not influenced by the presence of commonly encountered metal ions, and the detection limit was 1.71 × 10−8 M (1.1 ppb). As a practical application, the determination of Cu2+ in simulated semiconductor wastewater was conducted using a smartphone as a portable signal detection tool. For the color test analysis, enhanced reproducibility of Cu2+-sensing was realized using the grayscale image rather than the red, green, or blue channel image.



中文翻译:

基于2-(2-氨基苯基)苯并噻唑的氨基脲衍生物水解的Cu 2+选择性荧光探针

基于2-(2-氨基苯基)苯并噻唑的含氨基脲衍生物的新的基于Cu 2+的基于选择性反应的荧光探针1已经被开发。设计的探针1表现出对Cu 2+离子比对其他环境相关金属离子更显着的开启型荧光信号传导行为。探针1的信号传导是由于Cu 2+诱导的氨基脲部分水解形成了其强烈的荧光母体染料。探针1的Cu 2+信号转导不受常见金属离子的影响,检出限为1.71×10 -8 M(1.1 ppb)。在实际应用中,使用智能手机作为便携式信号检测工具进行了模拟半导体废水中Cu 2+的测定。对于颜色测试分析,使用灰度图像而不是红色,绿色或蓝色通道图像可实现增强的Cu 2+传感重现性。

更新日期:2017-11-13
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